本综述系统的介绍了石墨烯及氧化石墨烯。详实的讲述了石墨、石墨烯、氧化石墨、氧化石墨烯等概念,并详细介绍了湿法化学合成氧化石墨烯和石墨烯的方法,和非共价及共价改性石墨烯的方法。最后详细介绍了氧化石墨烯的功能化,包括氧化石墨烯的降解,含氧石墨烯功能基团的转化等。综上所述,本综述对石墨烯与氧化石墨烯的研究有很强的指导意义。
Chemistry with Graphene and Graphene Oxide—Challenges for Synthetic Chemists 共19页 引文149篇
Siegfried Eigler* and Andreas Hirsch*
Dr. S. Eigler, Prof. Dr. A. Hirsch
Friedrich-Alexander-Universitt Erlangen-Nrnberg (FAU)
Department Chemie und Pharmazie and Institut fr Neue Materialien und Prozesstechnik (ZMP)
Henkestrasse 42, 91054 Erlangen (Germany)
Dr.-Mack Strasse 81, 90762 Frth (Germany)
E-mail: siegfried.eigler@fau.de andreas.hirsch@fau.de
The chemical production of graphene as well as its controlled wet chemical modification is a challenge for synthetic chemists. Furthermore, the characterization of reaction products requires sophisticated analytical methods. In this Review we first describe the structure of graphene and graphene oxide and then outline the most important synthetic methods that are used for the production of these carbon-based nanomaterials. We summarize the state-of-the-art for their chemical functionalization by noncovalent and covalent approaches. We put special emphasis on the differentiation of the terms graphite,graphene, graphite oxide, and graphene oxide. An improved fundamental knowledge of the structure and the chemical properties of graphene and graphene oxide is an important prerequisite for the development of practical applications.
[emuch.net],DanaInfo=onlinelibrary.wiley.com 7720_ftp.pdf
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