上海师范大学邓清海教授课题组招收2018年有机化学 专业型研究生1名
学校: | 上海师大 | 专业: | 工学->化学工程与技术->应用化学
| 年级: | 2018 | 招生人数: | 1 | 招生状态: | 正在招生中 |
上海师范大学东方学者邓清海特聘教授课题组招收2018年有机化学 专业型研究生1名。专业课必须要考数学,另一门专业课考有机化学者 优先
有意者请提供大学本科成绩单,研究生初试成绩以及自我简介,发信至qinghaideng@shnu.edu.cn。
邓清海(DENG Qing-Hai) 教授:
上海市东方学者。2003年于武汉大学化学与分子科学学院获理学学士学位;2009年于中国科学院上海有机化学研究所获理学博士学位,师从支志明院士(香港大学);2010-2012年获德国洪堡基金会资助于德国海德堡大学从事博士后研究;2012-2014年获海德堡大学和巴斯夫公司资助于海德堡催化研究实验室从事博士后研究;2015年加入上海师范大学。
Email: qinghaideng@shnu.edu.cn
研究方向:(1) 新型配体的设计、合成及应用;(2) 不对称催化;(3) 金属催化的C-N键形成反应
主持项目:
1.上海市特聘教授(东方学者),上海市教委高端人才引进项目,2013-2016;
2.新型手性钳形协同配体的合成及其在不对称催化中的应用研究,国家自然科学基金(青年项目),2015-2017;
3.新型手性协同配体的设计及其在仿生催化中的应用研究, 上海市人才发展资金,2016- 2018。
4.手性钳形协同配体在不对称氢转移反应中的应用和机理研究, 上海市青年科技启明星计划,2016- 2019。
5.基于二吡咯亚甲基骨架的NNNN型手性光敏配体的合成及其在不对称光致氧气氧化反应中的应用研究,国家自然科学基金面上项目,2018- 2021。
课题组具体介绍请见: http://shenghuan.shnu.edu.cn/6d/d5/c15283a355797/page.htm
发表文章和专利:
1. Q. Ye, M. Jiang*, Q.-H. Deng*, J.-T. Liu. Copper-catalyzed Intramolecular Carbotrifluoromethylation of Ene-Imines for the Construction of 3-(2,2,2-Trifluoro)ethylated 4-Amino-Chromans. Adv. Synth. Catal. 2018, 10.1002/adsc.201701298
2. Z.-R. Li, D.-Q. Wu, J. Sun, J. Shen, Q.-H. Deng*. Metal-Free Azidoarylation of Vinylcyclopropanes for the Synthesis of N3-Containing Dihydronaphthalenes. Asian J. Org. Chem. 2018, 7, 432.
3. Z.-R. Li, X.-X. Bao, J. Sun, J. Shen, D.-Q. Wu, Y.-K. Liu, Q.-H. Deng*, F. Liu*. Iron-catalyzed trifluoromethylation of vinylcyclopropanes: facile synthesis of CF3– containing dihydronaphthalene derivatives. Org. Chem. Front. 2016, 3, 934.
4. T. Bleith#, Q.-H. Deng#, H. Wadepohl, L. H. Gade*. Radical Changes in Lewis Acid Catalysis: Matching Metal and Substrate. Angew. Chem. Int. Ed. 2016, 55, 7852.( # Co-first Authors)
5. Q.-H. Deng, R. L. Melen, L. H. Gade*. Anionic Chiral Tridentate N-Donor Pincer Ligands in Asymmetric Catalysis. Acc. Chem. Res. 2014, 47, 3162.
6. Q.-H. Deng, Rettenmeier, C., H. Wadepohl, L. H. Gade*. Copper-Boxmi Complexes as Highly Enantioselective Catalysts for Electrophilic Trifluoromethylthiolations. Chem. Eur. J. 2014, 20, 93. (Highlighted by “Synfacts 2014, 398.”)
7. Q.-H. Deng, T. Bleith, H. Wadepohl, L. H. Gade*. Enantioselective Iron-Catalyzed Azidation of β-Ketoesters and Oxindoles. J. Am. Chem. Soc. 2013, 135, 5356.
8. Q.-H. Deng, H. Wadepohl, L. H. Gade*. Highly Enantioselective Copper-Catalyzed Electrophilic Trifluoromethylation of β-Ketoesters. J. Am. Chem. Soc. 2012, 134, 10769. (Highlighted by “Synfacts 2012, 979.”)
9. Q.-H. Deng, H. Wadepohl, L. H. Gade*. Highly Enantioselective Copper-Catalyzed Alkylation of β-Ketoesters and Subsequent Cyclization to Spirolactones/Bi-spirolactones. J. Am. Chem. Soc. 2012, 134, 2946. (Highlighted by “Synfacts 2012, 512.”)
10. Q.-H. Deng, H. Wadepohl, L. H. Gade*. The Synthesis of a New Class of Chiral Pincer Ligands and Their Applications in Enantioselective Catalytic Fluorinations and the Nozaki-Hiyama-Kishi Reaction. Chem. Eur. J. 2011, 17, 14922.
11. J.-C. Wang, Z.-J. Xu, Z. Guo, Q.-H. Deng, C.-Y. Zhou, X.-L. Wan, C.-M. Che*. Highly Enantioselective Intermolecular Carbene Insertion to C–H and Si–H Bonds Catalyzed by a Chiral Iridium(III) Complex of a D4-symmetric Halterman Porphyrin Ligand. Chem. Commun. 2012, 48, 4299.
12. Q.-H. Deng, J.-C. Wang, Z.-J. Xu, C.-Y. Zhou, C.-M. Che*. Metal-Free Intramolecular Aziridination of Allylic Carbamates Mediated by Hypervalent Iodine Compounds. Synthesis, 2011, 18, 2959.
13. Q.-H. Deng, J. Chen, J.-S. Huang, S. S.-Y. Chui, N. Zhu, G.-Y. Li, C.-M. Che*. Trapping Reactive Metal-Carbene Complexes by a Bis-Pocket Porphyrin: X-ray Crystal Structures of Ru=CHCO2Et and trans-[Ru(CHR)(CO)] Species and Highly Selective Carbenoid Transfer Reactions. Chem. Eur. J. 2009, 15, 10707.
14. Q.-H. Deng, H.-W. Xu, A. W.-H. Yuen, Z.-J. Xu, C.-M. Che*. Ruthenium-Catalyzed One-Pot Carbenoid N-H Insertion Reactions and Diastereoselective Synthesis of Prolines. Org. Lett. 2008, 10, 1529. (Highlighted by “Synfacts 2008, 730.” and “Stereoselective C-N Ring Construction, D. F. Taber, Org. Chem. Highlights 2008, November 17.)
15. H.-Y. Thu, G. S.-M. Tong, J.-S. Huang, S. L.-F. Chan, Q.-H. Deng, C.-M. Che*. Highly Selective Metal Catalysts for Intermolecular Carbenoid Insertion into Primary C-H Bonds and Enantioselective C-C Bond Formation. Angew. Chem. Int. Ed. 2008, 47, 9747. (“Inside Cover” paper)
16. M. K.-W. Choi, W.-Y. Yu, M.-H. So, C.-Y. Zhou, Q.-H. Deng, C.-M. Che*. A Non-Cross-Linked Soluble Polystyrene-Supported Ruthenium Catalyst for Carbenoid Transfer Reactions. Chem. Asian J. 2008, 3, 1256.
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