地大和中南老师编写的相图热力学,感觉不错,下边是目录:
5.1 概述.........................................................................................................................................................1
5.2 相图实验测定方法.................................................................................................................................2
5.2.1 淬冷法.........................................................................................................................................2
5.2.2 热分析.........................................................................................................................................7
5.2.3 相图拓扑学及反应图...............................................................................................................13
5.3 相图热力学计算的一般原理...............................................................................................................20
5.4 常用热力学模型...................................................................................................................................22
5.4.1 纯组元和化学计量比化合物...................................................................................................23
5.4.2 溶体相和中间化合物...............................................................................................................23
5.4.3 磁性有序无序和化学有序无序对热力学性质的贡献...........................................................31
5.4.4 多元系热力学性质的外推方法...............................................................................................36
5.5 二元相图热力学计算实例...................................................................................................................40
5.5.1 液相和固相均完全互溶的同晶型二元相图计算...................................................................40
5.5.2 液相完全互溶,固相完全不互溶的简单共晶型二元相图计算...........................................42
5.5.3 液相完全互溶,固相部分互溶的共晶型二元相图计算.......................................................44
5.5.4 溶解度间隙的计算...................................................................................................................46
5.5.5 生成中间化合物的二元相图计算...........................................................................................48
5.5.6 亚稳相图计算...........................................................................................................................51
5.6 相图热力学计算常用软件.................................................................................................................53
5.6.1 Thermo-Calc.............................................................................................................................53
5.6.2 Factsage...................................................................................................................................58
5.6.3 Pandat.......................................................................................................................................62
5.7 相图的热力学优化计算实例...............................................................................................................65
5.8 多元相图测定及计算...........................................................................................................................69
相图热力学.part1.rar
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相图热力学.part2.rar
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